VoIP calls, using the network protocols SIP/SDP and RTP, are the de-facto standard when it comes to voice calls. Wireshark offers some special features to analyze those calls and RTP streams – even with a nice “Play Streams” option, which discretely decodes your calls. Ouch. Again and again, frightening which privacy-related protocols are completely unencrypted on the Internet!
Here are some hints for Wireshark as well as a downloadable pcap with three calls in there. ;) Have fun!